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26900 Molekylær Ladningsoverførsel i kemi og biologi: En introduktion til teorien |
| Engelsk titel: Molecular Charge Transport in Chemistry and Biology: An Introduction to the Theory |
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Sprog: Engelsk Point: 5,7, Ekstern censur.
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| Type: kursus på phd-niveau, udbydes under åben uddannelse |
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Skemaplacering: |
Forår
February - May
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Eksamensplacering: |
Aftales med læreren
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Undervisningsform: 14 weekly sessions with one or two lectures followed by organized seminar/discussion. |
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Evalueringsform: Mundtlig fremlæggelse og bedømmelse af opgave(r)
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| Karakter: bestået/ikke bestået |
| Faglige forudsætninger: Candidate training and interest in physics and chemistry |
Kursusmål: For Ph.D. students and others interested in chemical and biological charge transfer, and with an urge to approach charge transfer concepts and formalism beyond the trivial.
Contents: established and frontier elements of electron and atom group transfer in chemistry, biochemistry and biophysics. See course description. |
Kursusindhold: Established and frontier elements of electron and atom group transfer in chemistry, biochemistry and biophysics. Topics to be chosen from:
1.The quantum mechanical tunnel effect in physical, chemical, and biological systems.
2.The liquid state of the environmental reaction medium.
3.The simplest chemical process - electron transfer: outer sphere electron transfer in inorganic and organic chemistry; dissociative electron transfer.
4.Towards preciser electron transfer theory: nuclear tunnelling; chemical processes at low temperatures; the diabatic and adiabatic limits.
5.Optical electronic processes and charge transfer spectroscopy.
6.Proton and atom group transfer: general acid and base catalysis, kinetic isotope effects.
7.The electrochemical process: the solid-liquid interface; electron transfer at metal and semiconductor electrodes; electron densities and electron tunnelling.
8.The notion of "long-range" electron transfer; intermediate states and intermediate matter; environmental dynamics and electron tunnelling.
9.Electron transfer in proteins and nucleic acids: molecular recognition; coherent processes; the photosynthetic apparatus; enzyme function and conformational dynamics.
10.Solvation and resolvation dynamics - the stochastic approach.
11.Perspectives and outlook: chemical nanostructures; molecular electronics; scanning probe microscopy, STM and AFM; ultrafast processes; charge transfer and phase transitions. |
| Bemærkninger: Deadline 15. januar |
| Kontaktperson: Jens Ulstrup, building 207, (+45) 4525 2359, ju@kemi.dtu.dk |
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